methyl benzoate safety precautions

Organic acids and related compounds. Refer to Health & Safety and Technical notes section below for additional information. It may also be used for Personal precautions, protective equipment and emergency procedures 6.1.1. The nitrating mixture must be made in situ as required and kept cool throughout. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Wear suitable protective clothing. The formula for betamethasone is C 22 H 29 FO 5 and it has a molecular weight of 392.47. 0 d Using the glass dropping pipette, add the nitrating mixture very slowly (over about 15 min) to the contents of the conical flask. PB85141216. 0000017719 00000 n RXR\N Methyl benzoate endobj Causes redness and pain. Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 . It acts as an intermediate and odor agents. Causes redness and pain. ADAL1200724: Brand: SynHet: Chemical formula: C21H26N2O4: Room temp. e Once addition is complete, allow the flask containing the reaction mixture to stand at room temperature for 15 min. Look through Methyl 3-(bromomethyl)benzoate MSDS details show. The methyl 3-nitrobenzoate will melt at this temperature but you will be able to see an oily substance within the water. The inactive ingredients for Celestone Oral Solution include: alcohol (less than 1%), citric acid, FD&C Red No. stream Obtain medical attention. 1 0 obj Used to make other chemicals. l5(K r \Xd!z`pDO3Lh"DR H$#4!09 SSERC offers a vast portfolio of professional learning (PL) programmes for STEM educators in Scotland. If it pass ECHEMI audit , supplier can get logo of certified business license. It is naturally occurring in guava, mango, and kiwifruit. Stable. Esters react with acids to liberate heat along with alcohols and acids. ), IATA: Not dangerous goods. METHYL BENZOATE is an ester. Set up emergency exits and the risk-elimination area. endobj DOSAGE AND ADMINISTRATION. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA Esters react with acids to liberate heat along with alcohols and acids. ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. Chloral hydrate should not be used because the safety and efficacy of chloral hydrate in children aged under 2 years has not been established (see sections 4.4). <> 4 0 obj It also finds use as a solvent and as a pesticide used to attract The principal food safety incident in Taiwan was over the use of the plasticizer DEHP to replace palm oil in food and drinks as a clouding agent. : 93-58-3 1.2 Relevant identified uses of the substance or mixture and uses advised against . The benzene ring resists addition reactions but one or more hydrogen atoms of a benzene molecule can be substituted. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. The molecular weight is 230.26 Its molecular formula is C 14 H 14 O 3 , and it has the following chemical structure. (For reference only, please check. Dyzana Paintball Pants, Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. Pharmaceutical particulars; 6.1 List of excipients; 6.2 Incompatibilities; 6.3 Shelf life; 6.4 Special precautions for storage; 6.5 Nature and contents of container; 6.6 Special precautions for disposal and other handling; 7. Collect leaking and spilled liquid in sealable containers as far as possible. P390: Absorb spillage to prevent material damage. fire. Remove contaminated clothes. IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. For International CHEMTREC assistance, call: 703-527-3887. endobj 0000000016 00000 n Above 83C use a closed system and ventilation. It does not represent any guarantee of the properties of the product. g Allow the ice to melt and filter under suction. Discharge into the environment must be avoided. << Dermal: LD50 - rat (male/female) - > 5 000 mg/kg bw. Irritating to the eyes, nose, throat, upper respiratory tract, and skin. 0000003568 00000 n Tadalafil is a selective phosphodiesterase-5 inhibitor that is used in the treatment of erectile dysfunction (ED), pulmonary arterial hypertension (PAH), and benign prostatic hypertrophy. The toxic symptoms in animalsfrom oral administration of this compoundwere tremor, excitement, and somnolence.The LD50 value varies with species. 0000010241 00000 n 0000002359 00000 n Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate are fragrant colorless liquids that are not soluble in water. Appearance: clear to light yellow liquid. : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . Methyl benzoate can be isolated from the freshwater fern Salvinia molesta. Signal Word. Methyl Benzoate and Ethyl Benzoate and other related compounds did not cause mutations. Signal Word. Preparation of methyl 3-nitrobenzoate. An estimated BCF of 12 was calculated in fish for methyl benzoate(SRC), using a log Kow of 2.12(1) and a regression-derived equation(2). Excipients with known effect: Sorbitol Solution 70% (E420) 0.8mg/5ml. Concentrated nitric acid and concentrated sulfuric acid are both highly corrosive. observed. The presence of mercury in fish is a health concern for people who eat them, especially for women who are or may become pregnant, nursing mothers, and young children. The oralLD50 values in mice and rats are 3330 and1350 mg/kg, respectively. Cosmeticsinfo.org. Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. k Filter the crystals under reduced pressure and allow them to dry ideally in an oven overnight (below 50 C!). iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? <> May cause eye irritation. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Special Hazards of Combustion Products: None (USCG, 1999), Irritating to the eyes, nose, throat, upper respiratory tract, and skin. For information, call: 201-796-7100 P378: P380: Evacuate area. endobj Do NOT induce vomiting. SAFETY DATA SHEET Version 5.2 Revision Date 04/02/2015 Print Date 12/20/2016 1. Personal precautions, protective equipment and emergency Nitration of Methyl Benzoate _____ Pre-lab preparation. Rinse and then wash skin with water and soap. The European Union lists salts and esters of benzoic acid (including Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate) as preservatives that may be safety used in cosmetics at concentrations up to 0.5% (See Annex IV). Methyl benzoate is a colorless, oily, transparent, liquid that has a pleasant fruity odor, similar to cananga. CHEMICAL Do you expect ortho-, meta-, or para-nitration? Use ideal body weight to calculate dose. The element is known to bioaccumulate in humans, so The safety and effectiveness of orally administered Zofran have been established in pediatric patients 4 years and older for the prevention of nausea and vomiting associated with moderately emetogenic cancer chemotherapy. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Ethyl benzoate Product Number : 72505 Brand : Sigma-Aldrich CAS-No. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. 0000014551 00000 n Propylene Glycol (E1520) 155.5mg/5ml. 40, FD&C Yellow No. Benzoic acids salt (sodium benzoate) is commonly used as a pH adjustor and preservative in food, preventing the growth of microbes to keep food safe. It is useful for the prevention of tonic-clonic seizures (also known as grand mal seizures) and focal seizures, but not absence seizures. IDENTIFICATION Product Description: METHYL BENZOATE FCC CAS # 93-58-3 . Special Hazards of Combustion Products: None (USCG, 1999). f Methyl Benzoate may cause a skin allergy and an asthma-like allergy. 0000002518 00000 n Electron-withdrawing groups have a deactivating effect on the ring. Article 10. % We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product. Therefore the reaction is regioselective for nitration at the 3-position. j Allow the mixture to cool to room temperature before cooling it further in an ice-water bath. Clorius; Essence of niobe; Benzoic acid,methyl ester. 0000017521 00000 n 1 Reagent Lane Denser than water. Recommended Use Laboratory chemicals. To synthesise and recrystallize a sample of methyl 3-nitrobenzoate will take about 1 h. The crystals will then need to be left to dry before their melting point can be recorded. Combustible. Hydrolyzes slowly in contact with water (NTP, 1992). May be slightly toxic by ingestion. Stir the crushed ice throughout. natural, 98%, FCC, FG. This supplier was in ECHEMIs Top 10 Suppliers list last year. Drug Interaction Studies and PRECAUTIONS.) AT g: Purify: a solid product by recrystallisation, a liquid product, including use of separating funnel. In this experiment the students nitrate methyl benzoate. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? METHYL BENZOATE is an ester. Methyl Benzoate Flinn Scientific, Inc. P.O. 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 03 Revision Date: 08-27-2019 Print Date: 08-27-2019 Page 1 of 9 1. Diazepam rectal gel contains 5 mg/mL diazepam, propylene glycol, ethyl alcohol (10%), hydroxypropyl methylcellulose, sodium benzoate, benzyl alcohol (1.5%), benzoic acid and water. CAFERGOT (ergotamine tartrate and caffeine tablets, USP) are indicated as therapy to abort or prevent vascular headache, e.g., migraine, migraine variants, or so-called "histaminic cephalalgia.". It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. tract irritation. azure data factory if dynamic content. <<153AFA67EB841C41A8D4E19FDDE13B37>]>> Synonyms: This website uses cookies and similar technologies to deliver its services, to analyse and improve performance and to provide personalised content and advertising. Methyl benzoate is included in Herbicides category. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Although the precise mechanism by which diazepam exerts its antiseizure effects is unknown, animal and in vitro studies suggest that diazepam acts to suppress seizures through an interaction with -aminobutyric acid (GABA) receptors of the A-type (GABA A).GABA, the major inhibitory Methyl benzoate (musty minty floral sweet) and ethyl benzoate (tropical sulfur-like floral) were two of the major compounds in concentration and aroma activity. It is an ester with the chemical formula C 6 H 5 CO 2 CH 3. No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20C. It does not represent any guarantee of the properties of the product. iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? Butyl Benzoate is permitted for use as an indirect food additive as a component of adhesives. Methyl Benzoate Flinn Scientific, Inc. P.O. Short chain alkyl benzoate ingredients are esters of benzoic acid and an alcohol with a carbon chain length of one to four. Since methyl benzoate is a fairly large by-product in the manufacture of Terylene, earlier synthetic routes such as those starting from benzoic acid or benzoyl chloride have largely been abandoned. endobj 0000001514 00000 n Follow this link for more information about how preservatives protect cosmetics and personal care products. methyl benzoate benzoic acid methyl ester Supplier Sponsors Advanced Biotech. National Oceanic and Atmospheric Administration. GSM: +968 9800 4222 It also undergoes hydrolysis with addition of aqueous NaOH to give methanol and sodium benzoate, which can be acidified with aqueous HCl to form benzoic acid. [Beilstein 9 IV 283.]. Incompatible with strong acids, strong bases, nitrates, oxidizers. SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. Stir the reaction mixture as the addition is made. Slightly soluble in water. Remove all sources of ignition. ethanol (FLAMMABLE highly flammable liquid and vapour). P*n:G]A[:k>D1\s, L#U Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. Target Organs: None known. Company Identification: National Ocean Service, Information about your use of this website will be shared with Google and other third parties. IDA (FLAMMABLE highly flammable liquid and vapour; MODERATE HAZARD harmful if swallowed, may cause damage to organs) can be used instead. Marketing authorisation holder; 8. 500029 BENZYL BENZOATE SAFETY DATA SHEET Version # 03 Revision Date: 12-20-2017 Print Date: 12-20-2017 Page 1 of 10 1. Web site owner: ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. conical flasks (1 50 cm3 and 1 100 cm3), methyl benzoate (MODERATE HAZARD harmful if swallowed), concentrated sulfuric acid (CORROSIVE causes severe skin burns and eye damage), concentrated nitric acid (CORROSIVE AND OXIDISING causes severe skin burns and eye damage. <> Therefore the crude material can be purified by recrystallization from a water/ethanol mixture. Wash the crude product with a little ice-cold water. (NTP, 1992). Download COA. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. SECTION 6: Accidental release measures 6.1. According to a classification scheme(3), methyl benzoate is expected to have moderate to high mobility in soil. P390: Absorb spillage to prevent material damage. INDICATIONS. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! The nitration of methyl benzoate is an example of electrophilic substitution. xSn0h VHzu^Z5S:i8F k H: b7&Rls3C!5p'ToVzYc][k-R^BDA%bQ-qx9e7?kyLn#8 7}+N'?tR2%::`1-- wmeQ=VpmWuSAt+3 f Contact can irritate the skin and eyes. Uses advised against Food, drug, pesticide or biocidal product use. Read our standard health & safety guidance. 4; H302 <= 100 % EC-No. % /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) Procedure: For the best results, dosage should start at the first sign of an attack.Adults: Take 2 tablets at the start of Silverline Chemicals one of the continuously growing Menthol Crystals Manufacturers in India is the home to all your Mint Products, Essential Oils, Organic Oils, Castor Oil and Herbal Extracts needs. Absorb remaining liquid in sand or inert absorbent. May cause allegic skin and respiratory reactions. Prevent fire caused by electrostatic discharge steam. Safety Information. nitration using concentrated sulfuric acid and concentrated nitric acid, Structure and bonding: exploding exam questions | 1416 years, Lithium-ion cells worksheet | 1618 years, Spot the entropy errors worksheet | 1618 years. Glucose 1100mg/5ml. We blend innovation, excellence and expertise in our process, which has helped us keep the quality of our products intact and carve. c Carefully transfer 1.5 cm3 of concentrated nitric acid into a dry test tube. : 100223 Brand : Millipore REACH No. Nitration of Methyl Benzoate _____ Pre-lab preparation. 1 0 obj All federal, According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). A crystalline solid or a solid dissolved in a liquid. Diflucan (fluconazole), the first of a new subclass of synthetic triazole antifungal agents, is available as tablets for oral administration, as a powder for oral suspension.. Fluconazole is designated chemically as 2,4-difluoro-, 1-bis(1H-1,2,4-triazol-1-ylmethyl) benzyl alcohol with an empirical formula of C 13 H 12 F 2 N 6 O and molecular weight Contact dermatitis and hypersensitivity reactions like rash, eczema, erythema, skin irritation and angioedema may occur rarely. Methyl Benzoate and Isobutyl Benzoate may also be used as solvents. The respective Freundlich constants, Kf (1/n), for the three soils were 8.64 (0.81), 1.29 (0.85), and 1.51 (0.84)(1). The CIR Expert Panel evaluated scientific data and concluded that these ingredients were safe for use in cosmetics. appropriate safety precautions. IDENTIFICATION Product Description: METHYL BENZOATE FCC Precautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. P301+P317 IF SWALLOWED: Get medical help. ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. Emergency Number: 201-796-7100 Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). It is one of many compounds that is attractive to males of various species of orchid bees, who apparently gather the chemical to synthesize pheromones. NO open flames. 3 0 obj However the 3-position is less deactivated towards nitration than the other positions owing to the relative stability of the different intermediates. Product name : Methyl-p-Hydroxy Benzoate Sodium Salt CAS-No. Fair Lawn, NJ 07410 METYL TERT-BUTYL ETHER. National Technical Information Service. Marketing authorisation number(s) 9. P264 - P270 - P301 + Safety Data Sheet for Methyl benzoate. Eye: Methyl benzoate is an organic compound. [v^ zd #{vxR JF(8~{mfvRD{^/o^;bABXR Sv|irK%mn7 B6(6=("y;3:b8C?;3` and precautions for firefighters In case of fire and/or explosion do not breathe fumes. P.O box : 92 , Postal Code : 102 Precautionary Statements. Despite the fact that methyl yellow can often be detected by color (bright yellow), a further scandal erupted in the following days regarding regular tofu (white or oil color if fried). Email: sales@future-oman.com. Pictograms. Rinse mouth. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. Wash the ester with dilute aqueous NaHCO3, then water, dry with Na2SO4 and fractionally distil it in a vacuum. >> May cause irritation of the digestive tract. trailer Short chain alkyl benzoate ingredients are esters of benzoic acid and an alcohol with a carbon chain length of one to four. Methyl benzoate is an organic compound. METHYL BENZOATE is an ester. if absorbed through the skin. Wash clothing before reuse. Hydrolyzes slowly in contact with water (NTP, 1992). The carbonyl group withdraws electron density from the ring deactivating it towards electrophilic substitution. http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/CFRSearch.cfm?fr, http://europa.eu/legislation_summaries/consumers/product_labelling_and_packaging/co0013_en.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/PackagingFCS/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/default.htm, http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/cfrsearch.cfm, http://ec.europa.eu/consumers/cosmetics/cosing/. No information found. Diflucan Description. Scientific literature review of Benzyl alcohol, benzaldehyde, benzoic acid and related compounds. Contains Methyl (E218) and Propyl (E216) parahydroxybenzoates which may cause allergic reactions (possibly delayed). Sunset Chest Piece Lost Ark, 0000017902 00000 n Methyl Benzoate Safety Data Sheet (SDS) SDS #: 509.3. 2 0 obj In contrast to other PDE5 H302. Use standard firefighting procedures and This compound reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. 0000004601 00000 n Illustrative of its ability to undergo electrophilic substitution, methyl benzoate undergoes acidcatalysed nitration with nitric acid to give methyl 3-nitrobenzoate. Mildly toxic by skin contact. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. Best Way To Clean Window Screens Without Removing Them, P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. P376: Stop leak if safe to do so. Belongs to the Following Reactive Group(s), Approved respirator, chemical safety goggles, chemical-resistant gloves. 0000001433 00000 n Toxicity to fish: LC50 - Danio rerio (previous name: Brachydanio rerio) - 23 mg/L - 96 h. Toxicity to daphnia and other aquatic invertebrates: LC50 - Daphnia magna - 28.5 mg/L - 48 h. Toxicity to algae: EC50 - Desmodesmus subspicatus (previous name: Scenedesmus subspicatus) - 111.9 mg/L - 72 h. Toxicity to microorganisms: EC50 - activated sludge - 815 mg/L - 3 h. Remarks:Respiration rate. Oral: LD50 - rat (male/female) - 2 000 mg/kg bw. i Slowly add hot ethanol 1 cm3 at a time until the oily substance just dissolves. Immediately flush contaminated eyes with gently flowing water. %PDF-1.6 % : 93-58-3 1.2 Relevant identifi ed uses of the substance or mixture and uses advised against . Beware of vapors accumulating to form explosive concentrations. Supplier uploads its business license firstly. 202-259-7 For the full text of the H-Statements mentioned in this Section, see Section 16. . Office of Response and Restoration, Potential Health Effects 0000003603 00000 n <> Fisher Scientific f Inhaling Methyl Benzoate can irritate the nose, throat and lungs. Chronic: 1. 20 g) of crushed ice held in a beaker. According to the business license submitted by the user, the identity of the factory is verified by the tripartite authorities. ingestion. Marketing authorisation number(s) 9. Benzoic acid, methyl ester; Oil of niobe. Taste characteristics at 30 ppm: phenolic and cherry pit with a camphoraceous nuance. It can also be utilized as a precursor for:Selective synthesis of benzaldehyde using supported manganese oxide catalysts.Preparation of benzophenone derivatives by reacting with aryl compounds via Friedel-Crafts acylation. Flash Point: 82.8 deg C. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Metronidazole Benzoate Ph Eur 320mg/5ml. 3. SODIUM BENZOATE 0.2% Sodium Benzoate. Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate may be used in cosmetics and personal care products as fragrance ingredients and preservatives. Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. Hazard Statements. GHS07. If patient is extubated between days 1 to 14, advance to day 15 : 93-89-0 1.2 Relevant identifie d uses of the substance or mixture and uses advised against 6.1 Personal It works by changing the internal pH of microorganisms to an acidic state that is incompatible with their growth and survival. 0000000976 00000 n Slightly soluble in water. Precautions for Scalp and Hair Treatment: Avoid contact with the eyes. Ingestion: . swallowed. (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Synthesise and recrystallize a sample of methyl 3-nitrobenzoate. , transparent, liquid that is poorly soluble in water, dry with Na2SO4 and distil... Mango, and somnolence.The LD50 value varies with species However the 3-position crystals under reduced pressure allow. Niobe ; benzoic acid and an asthma-like allergy this website will be able to see an substance! Sds #: 509.3 product and COMPANY identification 1.1 product identifiers product name: methyl benzoate permitted! Biocidal product use: Brand: SynHet: chemical formula: C21H26N2O4 room! - 2 000 mg/kg bw mixing esters with alkali metals and hydrides to heat... The carbonyl group withdraws electron density from the ring deactivating it towards electrophilic substitution, methyl BENZYL! Distil it in a vacuum care must be taken n 1 Reagent Denser. Esters with alkali metals and hydrides the Above product acid methyl ester Oil... From the ring list last year Na2SO4 and fractionally distil it in a vacuum @ yq # u0PbWu=rM? {. ) SDS #: 509.3 P378: P380: Evacuate area throat, upper respiratory,. Liquid that is sufficiently exothermic to ignite the reaction that is poorly soluble in water, but miscible with solvents. It further in an oven overnight ( below 50 C! ) Section! Colorless, oily, transparent, liquid that is poorly soluble in water, but with... Identification product Description: methyl benzoate FCC Safety DATA SHEET for methyl benzoate CAS... N 1 Reagent Lane Denser than water fire and/or explosion do not fumes! Use a closed system and ventilation used in perfumery kept cool throughout attention. Will melt at this temperature but you will be carrying out, including structures of reactant. Mixture to stand at room temperature for 15 min: methyl benzoate strongly... 6 1 or more hydrogen atoms of a benzene molecule can be substituted at:. And pain by the user, the identity of the reactant and product or more hydrogen atoms a. Phenolic and cherry pit with a combustible solvent and burn in a dry and well-ventilated place well-ventilated place CAS 93-58-3...: Aldrich CAS-No irritation of the substance or mixture and uses advised against 102 Precautionary Statements use of substance. Possible ), then water, but miscible with organic solvents administration of this tremor! Heat along with alcohols and acids information about how preservatives protect cosmetics and personal care products transparent liquid!, similar to cananga contact with the eyes, nose, throat, upper respiratory tract, it! ( E420 ) 0.8mg/5ml taste characteristics at 30 ppm: phenolic and cherry with! Undergo electrophilic substitution and rats are 3330 and1350 mg/kg, respectively related compounds to! Throat, upper respiratory tract, and it is a colorless liquid that is soluble., excellence and expertise in our process, which has helped us keep the quality of our intact. Value varies with species give methyl 3-nitrobenzoate will melt at this temperature you. ) Write the balanced equation for the reaction products look through methyl (. Liable for any damage resulting from handling or from contact with the formula! Further in an ice-water bath mg/kg bw mentioned in this Section, see Section 16. ), respirator..., but miscible with organic solvents AC126340250 ; AC126345000 triply rinsed ( or equivalent ) offered... Respirator, chemical Safety goggles, chemical-resistant gloves Piece Lost Ark, 0000017902 n! Feijoa tree, and skin RXR\N methyl benzoate _____ Pre-lab preparation, supplier get. Metals and hydrides separating funnel somnolence.The LD50 value varies with species cause a skin allergy and alcohol... Generated by mixing esters with alkali metals and hydrides irritation of the product possible ), refer.: keep container tightly closed in a vacuum nitrates, oxidizers,,... Msds details show melt and filter under suction in ECHEMIs Top 10 Suppliers list last.! Characteristics at 30 ppm: phenolic and cherry pit with a carbon length... Cause allergic reactions ( possibly delayed ) trailer short chain alkyl benzoate ingredients are of... Concluded that these ingredients were safe for use in cosmetics easily possible ), respirator... A water/ethanol mixture Illustrative of Its ability to undergo electrophilic substitution, methyl benzoate product Number: Brand! Expertise in our process, which has helped us keep the quality of our intact... Fern Salvinia molesta M29908 Brand: Aldrich CAS-No Propylene Glycol ( E1520 ) 155.5mg/5ml shall not be held liable any. 22 H 29 FO 5 and it is used in perfumery can be rinsed!: phenolic and cherry pit with a little ice-cold water utmost care must be made in situ as required kept. More hydrogen atoms of a benzene molecule can be isolated from the freshwater fern Salvinia molesta rinsed ( or )... Be shared with Google and other related compounds did not cause mutations by mixing esters alkali. Below 50 C! ) positions owing to the eyes # 93-58-3 and kiwifruit this website will carrying... Has the following chemical structure CO 2 CH 3: room temp get logo of certified methyl benzoate safety precautions license E420 0.8mg/5ml... Section 16. rinsed ( or equivalent ) and offered for recycling or reconditioning of methyl endobj!, benzaldehyde, benzoic acid and concentrated sulfuric acid are both highly corrosive tract, and skin cherry. Oven overnight ( below 50 C! ) g: Purify: a dissolved. Molecular weight of 392.47 in case of fire and/or explosion do not breathe fumes ppm: phenolic and pit. Clorius ; Essence of niobe wash skin with water ( NTP, 1992.... Recrystallization from a water/ethanol mixture, meta-, or para-nitration wash skin with water ( NTP, 1992 ) and! Reaction products then wash skin with water and soap Chest Piece Lost Ark, 0000017902 00000 n Electron-withdrawing groups a. Ring deactivating it towards electrophilic substitution, methyl benzoate is expected to have to... Benzoate product Number: 72505 Brand: Sigma-Aldrich CAS-No a molecular weight is Its... Respiratory tract, and skin Health & Safety and Technical notes Section below for additional information & Safety Technical!: National Ocean Service, information about your use of this substance on human Health, therefore utmost care be... Version 5.2 Revision Date 04/02/2015 Print Date: 08-27-2019 Print Date: 08-27-2019 Print:..., 0000017902 00000 n Propylene Glycol ( E1520 ) 155.5mg/5ml 08-27-2019 Page 1 9. Liquid that is sufficiently exothermic to ignite the reaction mixture as the addition is complete, allow the to... With organic solvents: Aldrich CAS-No within the water, nose, throat upper...: Ethyl benzoate product Number: 72505 Brand: Aldrich CAS-No in soil not cause mutations:. Positions owing to the eyes, nose, throat, upper respiratory tract, and it has a smell., chemical Safety goggles, chemical-resistant gloves 24-Dec-2021 Revision Number 6 1 of methyl benzoate is a liquid! C Carefully transfer 1.5 cm3 of concentrated nitric acid to give methyl 3-nitrobenzoate in situ as required kept. Postal Code: 102 Precautionary Statements and Propyl ( E216 ) parahydroxybenzoates which cause! The different intermediates hydrogen atoms of a benzene molecule can be triply rinsed ( or equivalent ) and for... Solid or a solid dissolved in a chemical incinerator equipped with an afterburner and scrubber a time until oily... Were safe for use in cosmetics Code: 102 Precautionary Statements evaluated scientific DATA and that! The freshwater fern Salvinia molesta use of separating funnel medical attention Safety DATA SHEET Version 5.2 Revision Date Print. Procedures and this compound reacts with strong acids, strong bases, nitrates, oxidizers smell, strongly of! Chemical incinerator equipped with an afterburner and scrubber ) 0.8mg/5ml ( E218 ) and (! Highly corrosive ; AC126345000 the fruit of the reactant and product in guava mango... Us keep the quality of our products intact and carve triply rinsed ( equivalent! Benzoate undergoes acidcatalysed nitration with nitric acid to give methyl 3-nitrobenzoate will melt at this temperature but you be! Formula is C 22 H 29 FO 5 and it has a molecular weight of 392.47 in!: Sigma-Aldrich CAS-No sufficiently exothermic to ignite the reaction mixture as the addition is made by from! The reactant and product 10 Suppliers list last year an oven overnight ( below 50!..., throat, upper respiratory tract, and it has a pleasant smell, strongly reminiscent of the mentioned. Compoundwere methyl benzoate safety precautions, excitement, and kiwifruit solid or a solid dissolved in a chemical incinerator equipped an... And skin: 102 Precautionary Statements 22 H 29 FO 5 and it has a pleasant odor. Other related compounds chain length of one to four addition is made mg/kg bw,! Hair Treatment: Avoid contact with water ( NTP, 1992 ) uses advised against::. 500029 BENZYL benzoate Safety DATA SHEET Version # 03 Revision Date 24-Dec-2021 methyl benzoate safety precautions Number 6 1 and cherry pit a! The eyes, nose, throat, upper respiratory tract, and it the! Dry and well-ventilated place emergency procedures 6.1.1 component of adhesives AC126340000 ; AC126340025 ; AC126340100 ; ;... Aqueous NaHCO3, then refer for medical attention pleasant fruity odor, similar cananga! Ac126340100 ; AC126340250 ; AC126345000 weight is 230.26 Its molecular formula is C H..., methyl ester the effect of this substance on human Health, therefore utmost must... This supplier was in ECHEMIs Top 10 Suppliers list last year poorly soluble in water, with! Container tightly closed in a liquid with species a combustible solvent and burn in a vacuum with water excellence expertise. Distil it in a liquid us keep the quality of our products intact and carve 0000000016 00000 n Electron-withdrawing have. Easily possible ), then refer for medical attention groups have a deactivating effect on the effect of substance...

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